4.4       The crustal growth problem

 

The question of whether the crust has grown progressively over geological time, or maintained an approximately constant volume, is one of the most fundamental in geology, but has proved hard to answer conclusively. A review of the ‘crustal growth’ model by its most persistent critic (Armstrong, 1991) shows that Nd isotope data provide critical tests for alternative models. Hence, three of the most important lines of Nd isotope evidence will be examined here.

 

4.4.1    Crustal accretion ages

 

The ability of the Sm)Nd method to ‘see back’ through younger thermal events and measure the crustal formation ages of continental rocks makes the method ideally suited to chart the present-day age distribution of crustal basement. This yields an apparent profile of continental growth through time which does not take into account crustal recycling into the mantle. Nevertheless, it is an appropriate starting point for this subject.

 

            Attempts to map the age structure of the continents were begun using the Rb)Sr method (Hurley et al., 1962), before the development of Sm)Nd analysis. Hurley et al. compared Rb)Sr isochron ages with Sr model ages calculated assuming a mantle 87Sr/86Sr ratio of 0.708. On average the two values were correlated, leading them to suppose that the isochron ages dated the time of crustal extraction from a basic source. This was a good approach, although we now know that the Rb)Sr system is too easily reset to yield reliable crustal extraction ages for old terranes. (Also the mantle growth curve is less radiogenic than 0.708). Hurley et al. applied the method to the North American continent in order to calculate the approximate areas of crustal basement attributable to geological provinces of various ages (Fig. 4.30).

Fig. 4.30. Estimated area of North American crustal basement attributable to different Rb)Sr age provinces. a) Map showing provinces of different ages in Myr; b) histogram of growth rate against time. After Hurley et al. (1962).

 

            Hurley and Rand (1969) extended this approach to include two-thirds of the land area of the world (excluding the USSR and China, for which data were not available). K)Ar data were used to geographically extrapolate from the more limited set of Rb)Sr data, bearing in mind the tendency for the former to be reset. Rb)Sr model ages were calculated using an improved mantle 87Sr/86Sr growth curve, yielding values now somewhat older than apparent crystallisation ages. Hurley and Rand’s data are presented on a plot of cumulative crustal age distribution against time (Fig. 4.31). From these data it appeared that crustal growth was accelerating somewhat with time. However, more recent studies have yielded curves of different shapes.

 

            A study of comparable sweep to that of Hurley et al. (1962) was performed by Nelson and DePaolo (1985), who used Nd model ages to map the age structure of the basement of the United States. Nelson and DePaolo found Nd model ages substantially older than igneous crystallisation ages, leading to a greatly increased estimate of the rate of Lower Proterozoic crustal growth in the mid-continent. These data, along with recently published ages on the Canadian Shield, led to a dramatic increase in the estimated average age of the North American craton, compared with that of Hurley et al. (1962). This picture was reinforced by Patchett and Arndt (1986), who further amplified the estimated area of newly accreted Lower Proterozoic (1.9 Byr-old) crustal basement in North America. This has generated a ‘sigmoidal’ curve of crustal formation against time (Fig. 4.31) which suggests that the greatest rates of new crustal accretion occurred in the middle of Earth history.

 

            As more detailed model age mapping is performed in areas of old crustal basement it is likely that further increases in average crustal extraction age will be found. The Superior and Slave provinces of Canada provide good examples of this. Hurley et al. (1962) mapped the Superior craton as 2.7 Byr in age, a concept still widely held today. However, U)Pb geochronology has shown the presence of large areas of 3 Byr-old crust in the NW Superior Province (reviewed by Thurston et al., 1991). Similarly, the Slave province is largely a 2.7 Byr craton, but a small belt of tonalitic gneisses with Early Archean zircons yield TCHUR model ages of up to 4.1 Byr (Bowring et al., 1989). Therefore, continued mapping of old cratons will probably fill the dip in the Early ) Mid Archean segment of the sigmoid (Fig. 4.31), yielding a linear or concave-downwards curve of apparent crustal growth with time.

Fig. 4.31. Estimated continental growth rates on a cumulative basis. After Jacobsen (1988).

 

 

4.4.2    Sediment provenance ages

 

In response to proponents of the ‘continental growth’ model (e.g. Moorbath, 1976), Armstrong (1981) argued that the record of continental accretion documented by various methods (as above) did not prove that the continental area had actually grown over geological time. Armstrong argued that a model in which the continental area was approximately the same 4.5 Byr ago as it is today could also generate apparent continental growth with time, provided that the rate of crustal recycling into the mantle (by sediment subduction) was equal to the rate of new crustal formation above subduction zones.

 

            Undoubtedly, recycling of crust back into the mantle does occur on a significant scale. Old crustal terranes may be shortened by orogeny, then flattened again by erosion and sediment subduction. However, some sediment should be expected to escape the recycling process and provide a record of the old, recycled terrane. Therefore, the search for evidence of constancy or growth in the continental mass turned to the sedimentary record. The ability of the Nd model age method to ‘see back’ through erosion and sedimentation to an original crustal extraction event made it ideal for these studies.

 

            To study this problem, it is convenient to portray sediment data on a diagram of Nd model age (crustal residence age) against the stratigraphic depositional age of the sediment in question (Fig. 4.32). Sediments eroded from juvenile mantle-derived sources will have TCR = TSTRAT and lie on a ‘concordia’ line (Allegre and Rousseau, 1984). In contrast, reworking of older sediments without any input of juvenile material will displace compositions to the right along horizontal vectors. A compilation of data from several sources is shown in Fig. 4.32, including clastic sediments (Hamilton et al., 1983; O’Nions et al., 1983; Taylor et al., 1983; Allegre and Rousseau, 1984) and particulates from major river systems at the present day (Goldstein et al., 1984).

Fig. 4.32. Model age versus stratigraphic age diagram showing a compilation of early 1980s data from several clastic sediment studies. Crustal growth models A, B and C are discussed in the text. After Goldstein et al. (1984).

 

            Allegre and Rousseau (1984) compared the sediment data with various theoretical models for continental evolution involving different rates of continental growth through time (Fig. 4.32). A ‘big bang’ model (A), whereby the whole continental mass was extracted at ca. 4 Byr or before, was ruled out. Allegre and Rousseau argued that a model involving uniform growth of the continents from 3.8 Byr to the present (B) was a better fit to the data, but that the best fit was produced by a curved line (C), representing decreasing growth of the crust through time.

 

            Unfortunately this diagram is not as conclusive as it may appear, due to the great difficulty of determining a global average sediment provenance age at any given time from the very variable provenance ages in individual provinces. This makes the data very susceptible to sampling bias. One source of such bias is preferential recycling of old sediments relative to erosion of more juvenile cratonic material. This will exaggerate the slowing down of continental growth with time, appearing to favour models of type C over type B. Another source of bias is the neglect of young orogenic belts such as the accreted terranes of the Canadian Cordillera (Samson et al., 1989). The inclusion of such data in Fig. 4.32 would favour linear evolution models (type B), suggesting that crustal growth has not slowed significantly in the Phanerozoic.

 

            The interpretation of Fig. 4.32 is also heavily influenced by assumptions about the degree of recycling of sediment into the mantle. The so called ‘big bang’ model shown in Fig. 4.32 involves no recycling of crustal material into the mantle. This does not correspond to Armstrong’s model, which involves constant recycling of old crust into the mantle and its replacement by an equal volume of juvenile crust. Armstrong (1991) claimed that his model gave rise to a curve (shown in Fig. 4.33) which looks remarkably like the steady growth model in Fig. 4.32. It is clear then that young sediments provide much too loose a constraint on crustal growth models. Therefore, the argument must focus on the provenance ages of the oldest surviving sediments.

Fig. 4.33. Model age versus stratigraphic age diagram showing data of Dia et al. (1990) for clastic sedimentary rocks from South Africa. Curve shows provenance ages predicted by the crustal model of Armstrong (1981). After Armstrong (1991).

 

            Isua supracrustals from western Greenland, which are the oldest clastic sediments analysed, yield identical stratigraphic and Nd model ages of 3750 Myr, indicating that they did not incorporate a significant amount of older reworked crust. However, the data of Dia et al. (1990) from South Africa show surprisingly old provenance ages for Mid to Late Archean sediments. On balance, the sediment data seem to favour a crustal growth model, but ultimately the argument rests on a null hypothesis (no sediments with very old provenance have yet been seen, therefore none exist). This is an inherently weak argument upon which to base such an important conclusion. This weakness comes from the need for representative sampling of old crust using a sediment data set which is inherently very noisy.

 

 

4.4.3    Archean depleted mantle

 

An alternative route to assessing the volume of crust at a given time in Earth history is to measure the composition of the depleted reservoir which balances the enriched crustal reservoir, namely the upper mantle (section 6.2.1). Because the upper mantle is stirred by convection, we can expect to sample this reservoir (in ancient volcanism) in a much more representative fashion than the sampling of the enriched reservoir by ancient sediments. Hence, the problem of crustal growth may be soluble if we can determine the extent of mantle depletion in early Earth history. If there was a large volume of continental crust in the early Earth, there should be evidence for strong mantle depletion.

 

            In the mid 1980s, several studies revealed initial Nd isotope data for Early and Mid Archean rocks which lay well above the chondritic evolution line, and in some cases above the depleted mantle evolution line of Goldstein et al. (1984). Smith and Ludden (1989) argued that some of the strongly positive , Nd values calculated for early mafic rocks are in error due to incorrect age assignments. The Kambalda example has already been mentioned (section 4.1.2), and doubtless there are problems with some of the other data. However, they concluded that there are enough depleted mantle compositions in the Early Archean for the phenomenon to be real.

 

            Such evidence for very early depletion of the upper mantle presents a problem for the model in which continental crust grew progressively over Earth history. On the other hand, Armstrong (1991) argued that these data supported his model of no crustal growth. In order to examine this claim, the data compilation of Armstrong (1991) is shown in Fig. 4.34, together with an evolution line for the MORB source which he claimed was a product of his 1981 model. However, most of the available Nd data can be satisfied by a less extreme evolution line in Fig. 4.34 (solid line), which is sub-parallel to DePaolo’s curve since 4 Byr ago. The solid evolution line represents the composition of the most depleted mantle sources, whereas DePaolo’s line represents the source of arc magmatism, which is generally less depleted.

Fig. 4.34. Initial , Nd for terrestrial rocks, compiled by Armstrong (1991), compared with his ‘big bang’ MORB evolution line. Solid curve is an alternative MORB depletion line for a crustal growth model. Note that this is not expected to agree with the dashed arc-source model of DePaolo (1981).

 

            The gradual depletion of the upper mantle which is portrayed by the solid line in Fig. 4.34 can only be reconciled with a constant-crustal-volume model if the average composition of the crust changes over geological time. In principle this requirement is satisfied in a model where the Earth begins its evolution with a thick basaltic (‘oceanic’) crust, which is gradually replaced by continental crust over geological time. This involves a non-plate tectonic model for Archean crustal evolution (e.g. West, 1980). A similar model was also supported by Galer and Goldstein (1991), who proposed that a thick, long-lived alkali basalt crust was built up in the Archean by small-degree melting of the deep mantle. However, as evidence mounts for earlier and earlier operation of plate tectonic processes in Earth history (e.g. Williams et al., 1992), there seems little reason to invoke a prolonged pre-plate tectonic era.

 

            Chase and Patchett (1988) proposed that accelerated early mantle depletion is in fact consistent with plate tectonic processes. They postulated that the storage of subducted oceanic crust in the mantle, before re-homogenisation with the depleted mantle (by convection), would give rise to a hidden enriched reservoir in the deep mantle to balance early depleted mantle. According to this model, the amount of ‘stored’ subducted oceanic crust has grown over Earth history, although  gradual cooling of the earth prevents the system from reaching a steady state by increasing the lifetime of subducted crust over geological time. Taking the cooling process into account, a duration of several hundred Myr to establish Early Archean mantle depletion is consistent with evidence for a 1 ) 2 Byr present-day lifetime of subducted oceanic crust, as deduced from ocean island basalts (section 6.3.1).

 

 

4.4.4    Early Archean crustal provinces

 

            Evidence for open system behaviour of Sm-Nd in komatiites (section 4.3.3) casts doubt on some of the evidence for strong mantle depletion during the Earth’s early history. However, new evidence for early depletion of the mantle was provided by Bennett et al. (1993) and Bowring and Housh (1995) based on the analysis of granitoid orthogneisses from Western Greenland and the Slave Province of northern Canada. Since these rock types are generally resistant to metamorphic Nd disturbance, the new evidence for Early Archean depleted mantle appeared much stronger. However, the new evidence was itself challenged by Moorbath and Whitehouse (1996) and Moorbath et al. (1997). Since this discussion has critical implications for crust–mantle evolution it will be examined in some detail, beginning with the data from the Acasta gneisses of the Slave Province.

 

            Bowring and Housh (1995) used SHRIMP U–Pb ages to calculate Nd initial ratios for a variety of rock types from Early Archean Acasta gneisses, from 3.6 to 4.0 Byr age, yielding , Nd values as high as +4 and as low as –5 (Fig. 4.35). However, Moorbath and Whitehouse  (1996) observed that most of the suite analysed by Bowring and Housh lay on an ‘errorchron’ (section 2.6.3) with an age of ca. 3.3 Byr, which they attributed to an intense metamorphic event which partially homogenised whole-rock Sm-Nd systems at that time. This result was later confirmed (Moorbath et al., 1997) by the analysis of  20 new samples, yielding a  combined errorchron age of 3370 " 60 Myr and initial ratio (, Nd) of  -5.6 (Fig. 4.35). Hence, they argued that , Nd values calculated at the U–Pb crystallisation ages of 3.6 to 4.0 Byr were not accurate measures of the magma source compositions at those times.

Fig. 4.35. Nd isotope evolution diagram showing initial , Nd values calculated at the various U/Pb ages of the Acasta gneisses ( ! ) compared with the initial ratio of a 3.3 Byr old best-fit errorchron. The outer envelope of Nd isotope growth curves is shown for reference. After Moorbath et al. (1997).

 

            Bowring and Housh (1996) argued in reply that the 3.3 Byr errorchron age could itself be a mixing line with no age significance. However, Moorbath et al. (1997) showed that there was no correlation between Nd isotope ratios and Nd concentrations in the Acasta gneisses, as would be expected from a mixing line. Such a mixing line was seen in Archean lavas from the Abitibi Belt of Ontario which had been contaminated with crustal material (Fig. 4.7). Moorbath et al. also argued that the relatively low MSWD value for their own Acasta samples (8.8) could not be explained by a fortuitous combination of short segments of 3.8 Byr isochrons, since this would yield a much higher MSWD value of several hundred. From this evidence, it appears that the  3.3 Byr old errorchron may date a real geological event (or series of events) which caused homogenisation of Sm-Nd systems in the Acasta gneisses. Since this event postdates the oldest zircon ages by up to 600 Myr, it is concluded that reliable initial , values for the mantle source cannot be calculated.

 

            Early Archean rocks from western Greenland represent the other principal source of evidence  about the composition of the Early Archean mantle. Evidence for strongly depleted mantle sources was first found in the Isua supracrustal sequence (e.g. Hamilton et al., 1983), and was supported by analysis of Amitsoq gneisses, and mafic enclaves in these gneisses named the Akilia suite (Bennett et al., 1993). The upper envelope of these three suites defines an evolution line for highly depleted mantle in the Early Archean (Fig. 4.36). This led Bennett et al. to propose a model of two stage evolution in the early Earth, in which early intense mantle depletion was followed by a period of mixing with deeper less depleted mantle, causing an inflection in the depleted mantle evolution line.

Fig. 4.36. Nd isotope evolution plot showing , Nd values of Bennett et al. (1993) at the ages determined by U–Pb analysis. ( ! ) = Amitsoq gneiss; ( " ) = Akilia enclaves in Amitsoq gneisses; shaded zone = Isua supracrustals. Large diamonds indicate ages and initial ratios for three SmNd errorchrons of Moorbath et al. (1997).

 

            However, Moorbath et al. (1997) showed that Akilia, Amitsoq and Isua suites all yield Sm-Nd errorchrons with ages significantly younger than SHRIMP U–Pb zircon ages. This suggested to Moorbath et al. that the SmNd systems in many of these rocks had been reset in a manner similar to the Acasta gneisses. However, this critique was itself the subject of a scientific discussion (Bennett and Nutman, 1998; Kamber et al., 1998), after which further debate was continued by Kamber and Moorbath (1998), Whitehouse et al. (1999) and Nutman et al. (2000). Since space here is limited, the present author will give only a brief overview of the debate.

 

            The belt of Early Archean rocks in west Greenland runs in a northeasterly direction parallel to Godhabsfjord, from Amitsoq on the coast, to Isua at the edge of the inland ice field. Based on detailed SHRIMP U–Pb analysis (see section 5.2.3 for the method), it now appears that this belt (termed the Itsaq gneiss complex) was created in two main events. Near Isua in the north, most U–Pb ages cluster around 3.8 Byr, which appears to be the age of the earliest crust-forming event in the area (Nutman et al., 2000). However, near Amitsoq in the south, most U–Pb ages cluster round 3.65 Byr, but zircons sometimes have cores up to 3.8 Byr in age. Furthermore, in the latter area, whole-rock RbSr, PbPb and SmNd errorchrons all give ages around 3.65 Byr (Whitehouse et al. 1999). This suggests that most of the crust in the south is 3.65 Byr old, but contains inherited fragments of 3.8 Byr old material. We can infer from this that any fragments of 3.8 Byr old rocks in the south probably had their Nd isotope systems reset 3.65 Byr ago, but the extent to which the rocks in the north preserve an accurate 3.8 Byr old initial ratio is unclear.

 

            The Amitsoq gneisses analysed by Bennett et al. (1993) came from both ends and the middle of the Itsaq gneiss complex. On the SmNd isochron diagram (Moorbath et al., 1997) these samples had much more scatter than 26 Amitsoq gneisses from the southern end of the belt, which defined an errorchron age of 3640  " 120 Myr (MSWD = 10) with an initial , Nd value of + 0.9 " 1.4 (Fig. 4.37). Unfortunately there were not enough Nd isotope analyses from the northern area of the gneiss complex, where old U–Pb ages predominate, to see whether this part of the complex had consistently different Nd isotope signatures from the southern part. Therefore, Moorbath et al. suggested that the generally increased scatter in the suite analysed by Bennett et al. was more likely due to later partial metamorphic disturbance during Late Archean or Mid Proterozoic events. They were not able to prove that resetting had occurred, although Hf isotope analysis (section 9.2.3) suggested that this might be the case, because the extremely positive , Nd values determined by Bennett et al. were not matched by similarly positive , Hf values.

Fig. 4.37. SmNd isochron diagram showing Amitsoq gneisses of the Itsaq gneiss complex. ( ! ) = southern suite of gneisses which define a 3640 Myr errorchron. ( " ) = more scattered data of Bennett et al. (1993). After Moorbath et al. (1997).

 

            When Moorbath et al. (1997) examined Nd data for five samples of Akilia mafic enclaves analysed by Bennett et al. (1993), they discovered a very strong linear array with an age of 3675 " 48 Myr and an initial ratio of + 2.6 " 0.4 , units (Fig. 4.38). The low MSWD of 2.1 for this regression makes it statistically an isochron, but since U–Pb ages for the gneissic host rocks range from 3784 to 3872 Myr, Moorbath et al. interpreted the age as an isotopic homogenisation event associated with the engulfing of the enclaves by the Amitsoq magmas. Bennett and Nutman (1998) countered that these samples came from too wide an area to be attributed to metamorphic homogenisation, and in response Kamber et al. (1998) reinterpreted the SmNd age for the enclaves as intrusive, and attributed the older U–Pb ages in the host gneisses to inherited zircons.

 

            Unfortunately, these interpretations are also equivocal, due to the small size of the sample suite. Four of the five samples analysed are from the southern area of the gneiss complex where the host gneisses are generally of 3.65 Byr age. Hence, in this area, both the isotope homogenisation model of Moorbath et al. (1997) and the young intrusive age proposed by Kamber et al.(1998) can explain the 3675 Myr array. Only one enclave from the northern area was analysed, although three duplicates were determined. This sample appears to be more than 3.8 Byr old, but since it has the same Nd isotope signature as the host rocks, it cannot be proven that the sample has not been isotopically homogenised with the host rocks at some time. Hence, this sample might provide evidence for very depleted Early Archean mantle, but it is very risky to base such a model on a single sample.

Fig. 4.38. Sm-Nd isochron for Akilia enclaves in the Amitsoq gneisses. Inset shows Nd isotope evolution lines for four samples. Shaded box shows range of U-Pb ages. After Moorbath et al. (1997).

 

            It is concluded from the above discussion that the re-setting model of Moorbath et al. (1997) does not apply to most of the western Greenland rocks, but nevertheless, the extremely depleted , Nd values proposed by Bennett et al. (1993) remain unproven in the face of the geologically complex  evolution of these rocks, and in the face of Hf isotope evidence (section 9.2.3). A more conclusive determination of Early Archean Nd isotope signatures must depend on the analysis of a larger number of samples from the northern part of the Itsaq gneiss complex, where 3.8 Byr old rocks seem to dominate. This shows that geochemical deductions are only as good as the geological sampling, even in one of the world’s most inaccessible field localities.

 

 

References

 

Albarede, F. and Goldstein, S. L. (1992). World map of Nd isotopes in sea-floor ferromanganese deposits. Geology 20, 761–3.

 

Allegre, C. J. and Rousseau, D. (1984). The growth of the continents through geological time studied by Nd isotope analysis of shales. Earth Planet. Sci. Lett. 67, 19)34.

 

Armstrong, R. L. (1981). Radiogenic isotopes: the case for crustal recycling on a near steady-state no-continental-growth Earth. Phil. Trans. Roy. Soc. Lond. A301, 443)72.

 

Armstrong, R. L. (1991). The persistent myth of crustal growth. Aust. J. Earth Sci. 38, 613)30.

 

Arndt, N. T. and Goldstein, S. L. (1987). Use and abuse of crust-formation ages. Geology 15, 893)5.

 

Awwiller, D. N. and Mack, L. E. (1991). Diagenetic modification of Sm)Nd model ages in Tertiary sandstones and shales, Texas Gulf Coast. Geology 19, 311)14.

 

Barovich, K. M. and Patchett, P. J. (1992). Behaviour of isotopic systematics during deformation and metamorphism: a Hf, Nd and Sr isotopic study of mylonitized granite. Contrib. Mineral. Petrol. 109, 386)93.

 

Bennett, V. C. and DePaolo, D. J. (1987). Proterozoic crustal history of the western United States as determined by neodymium isotope mapping. Geol. Soc. Amer. Bull. 99, 674–85.

 

Bennett, V. C. and Nutman, A. P. (1998). Extreme Nd-isotope heterogeneity in the early Archean-- fact or fiction? Case histories from northern Canada and West Greenland– Comment. Chem. Geol. 148, 213–7.

 

Bennett, V. C., Nutman, A. P. and McCulloch, M. T. (1993). Nd isotopic evidence for transient, highly depleted mantle reservoirs in the early history of the Earth. Earth Planet. Sci. Lett. 119, 299)317.

 

Bertram, C. J. and Elderfield, H. (1993). The geochemical balance of the rare earth elements and Nd isotopes in the oceans. Geochim. Cosmochim. Acta 57, 1957–86.

 

Bock, B., McLennan, S. M. and Hanson, G. N. (1994). Rare earth element redistribution and its effects on the neodymium isotope system in the Austin Glen Member of the Normanskill Formation, New York, USA. Geochim. Cosmochim. Acta 58, 5245)53.

 

Bowring, S. A. and Housh, T. (1995). The Earth’s early evolution: Science 269, 1535–40.

 

Bowring, S. A. and Housh, T. (1996). SmNd isotope data and Earth’s evolution: Reply. Science 273, 1878–9.

 

Bowring, S. A., King, J. E., Housh, T. B., Isachsen, C. E. and Podosek, F. A. (1989). Neodymium and lead isotope evidence for enriched early Archean crust in North America. Nature 340, 222)5.

 

Bros, R., Stille, P., Gauthier-Lafaye, F., Weber, F. and Clauer, N. (1992). Sm)Nd isotopic dating of Proterozoic clay material: an example from the Francevillian sedimentary series, Gabon. Earth Planet. Sci. Lett. 113, 207)18.

 

Burton, K. W., Lee, D.-C., Christensen, J. N., Halliday, A. N. and Hein, J. R. (1999). Actual timing of neodymium isotopic variations recorded by Fe–Mn crusts in the western North Atlantic. Earth Planet. Sci. Lett. 171, 149)56.

 

Burton, K. W., Ling, H.-F. and O’Nions, R. K. (1997). Closure of the Central American Isthmus and its effect on deep-water formation in the North Atlantic. Nature 386, 382–5.

 

Burton, K. W. and O’Nions, R. K. (1991). High-resolution garnet chronometry and the rates of metamorphic processes. Earth Planet. Sci. Lett. 107, 649)71.

 

Burton, K. W. and Vance, D. (2000). Glacial–interglacial variations in the neodymium isotope composition of seawater in the Bay of Bengal recorded by planktonic foraminifera. Earth Planet. Sci. Lett. 176, 425)41.

 

Cattell, A., Krogh, T. E. and Arndt, N. T. (1984). Conflicting Sm)Nd whole rock and U)Pb zircon ages for Archean lavas from Newton Township, Abitibi Belt, Ontario. Earth Planet. Sci. Lett. 70, 280)90.

 

Chapman, H. J. and Moorbath, S. (1977). Lead isotope measurements from the oldest recognised Lewisian gneisses of north-west Scotland. Nature 268, 41)2.

 

Chase, C. G. and Patchett, P. J. (1988). Stored mafic/ultramafic crust and early Archean mantle depletion. Earth Planet. Sci. Lett. 91, 66)72.

 

Chauvel, C., Dupre, B. and Jenner, G. A. (1985). The Sm)Nd age of Kambalda volcanics is 500 Ma too old! Earth Planet. Sci. Lett. 74, 315)324.

 

Chauvel C., Hofmann, A. W. and Arndt, N. T. (1983). New evidence for early mantle depletion from Nd isotopes in greenstones. Terra Cognita 3, 129 (abstract).

 

Chester, R., Griffiths, A. G. and Hirst, J. M. (1979). The influence of soil-sized atmospheric particulates on the elemental chemistry of deep sea sediments of the northeastern Atlantic. Marine Geol. 32, 141–54.

 

Claoue-Long, J. C., Thirlwall, M. F. and Nesbitt, R. W. (1984). Revised Sm-Nd systematics of Kambalda greenstones, Western Australia. Nature 307, 697)701.

 

Compston, W., Williams, I. S., Campbell, I. H. and Gresham, J. J. (1985). Zircon xenocrysts from the Kambalda volcanics: age constraints and direct evidence for older continental crust below the Kambalda-Norseman greenstones. Earth Planet. Sci. Lett. 76, 299)311.

 

Cullers, R. L., Bock, B. and Guidotti, C. (1997). Elemental distributions and neodymium isotopic compositions of Silurian metasediments, western Maine, USA: Redistribution of rare earth elements. Geochim. Cosmochim. Acta 61, 1847)61.

 

DePaolo, D. J. (1981). Neodymium isotopes in the Colorado Front Range and crust)mantle evolution in the Proterozoic. Nature 291, 193)7.

 

DePaolo, D. J. and Wasserburg, G. J. (1976a). Nd isotopic variations and petrogenetic models. Geophys. Res. Lett. 3, 249)52.

 

DePaolo, D. J. and Wasserburg, G. J. (1976b). Inferences about magma sources and mantle structure from variations of 143Nd/144Nd. Geophys. Res. Lett. 3, 743)6.

 

DePaolo, D. J. and Wasserburg, G. J. (1979). Sm)Nd age of the Stillwater complex and the mantle evolution curve for neodymium. Geochim. Cosmochim. Acta 43, 999)1008.

 

Dia, A., Allegre, C. J. and Erlank, A. J. (1990). The development of continental crust through geological time: the South African case. Earth Planet. Sci. Lett. 98, 74)89.

 

Dickin, A. P. (2000). Crustal formation in the Grenville Province: Nd-isotope evidence. Can. J. Earth Sci. 37, 165–81.

 

Frank, M. (2002). Radiogenic isotopes: tracers of past ocean circulation and erosional input. Rev. Geophys. 40 (1), 1)38

 

Frank, M., O’Nions, R. K., Hein, J. R. and Banakar, V. K. (1999a). 60 Myr records of major elements and PbNd isotopes from hydrogenous ferromanganese crusts: Reconstruction of seawater paleochemistry. Geochim. Cosmochim. Acta 63, 1689)1708.

 

Frank, M., Reynolds, B. C. and O’Nions, R. K. (1999b). Nd and Pb isotopes in Atlantic and pacific water masses before and after closure of the Panama gateway. Geology 27, 1147)50.

 

Galer, S. J. G. and Goldstein, S. L. (1991). Early mantle differentiation and its thermal consequences. Geochim. Cosmochim. Acta 55, 227)39.

 

Goldberg, E. D., Koide, M., Schmidt, R. A. and Smith, R. H. (1963). Rare earth distributions in the marine environment. J. Geophys. Res. 68, 4209)17.

 

Goldstein, S. L. and Jacobsen, S. B. (1987). The Nd and Sr isotopic systematics of river-water dissolved material: implications for the sources of Nd and Sr in seawater. Chem. Geol. (Isot. Geosci. Section) 66, 245)72.

 

Goldstein, S. L. and Jacobsen, S. B. (1988). Nd and Sr isotopic systematics of river water suspended material: implications for crustal evolution. Earth Planet. Sci. Lett. 87, 249)65.

 

Goldstein, S. L., O’Nions, R. K. and Hamilton, P. J. (1984). A Sm)Nd isotopic study of atmospheric dusts and particulates from major river systems. Earth Planet. Sci. Lett. 70, 221)36.

 

Green, T. H., Brunfeldt, A. O. and Heier, K. S. (1969). Rare earth element distribution in anorthosites and associated high grade metamorphic rocks, Lofoten-Vesteraalen, Norway. Earth Planet. Sci. Lett. 7, 93)8.

 

Griffin, W. L. and Brueckner, H. K. (1980). Caledonian Sm)Nd ages and a crustal origin for Norwegian eclogites. Nature 285, 319)20.

 

Hamilton, P. J., Evensen, N. M., O’Nions, R. K. and Tarney, J. (1979). Sm)Nd systematics of Lewisian gneisses : Implications for the origin of granulites. Nature 277, 25)8.

 

Hamilton, P. J., O’Nions, R. K., Bridgwater, D. and Nutman, A. (1983). Sm)Nd studies of Archean metasediments and metavolcanics from West Greenland and their implications for the Earth’s early history. Earth Planet. Sci. Lett. 62, 263)72.

 

Hanson, G. N. (1978). The application of trace elements to the petrogenesis of igneous rocks of granitic composition. Earth Planet. Sci. Lett. 38, 26)43.

 

Harper, C. L. and Jacobsen, S. B. (1992). Evidence from coupled 147Sm)143Nd and 146Sm)142Nd systematics for very early (4.5-Gyr) differentiation of the Earth’s mantle. Nature 360, 728)32.

 

Haskin, L. A., Frey, F. A., Schmidt, P. A. and Smith, R. H. (1966). Meteoritic, solar and terrestrial rare-earth distributions. Phys. Chem. Earth 7, 167)321.

 

Hurley, P. M., Hughes, H., Faure, G., Fairbairn, H. W. and Pinson, W. H. (1962). Radiogenic strontium-87 model of continent formation. J. Geophys. Res. 67, 5315)34.

 

Hurley, P. M. and Rand, J. R. (1969). Pre-drift continental nuclei. Science 164, 1229)42.

 

Ingram, B. L., Hein, J. R. and Farmer, G. L. (1990). Age determinations and growth rates of Pacific ferromanganese deposits using strontium isotopes. Geochim. Cosmochim. Acta 54, 1709)1721.

 

Jacobsen, S. B. (1988). Isotopic constraints on crustal growth and recycling. Earth Planet. Sci. Lett. 90, 315)29.

 

Jacobsen, S. B. and Pimentel-Klose, M. R. (1988). Nd isotopic variations in Precambrian banded iron formations. Geophys. Res. Lett. 15, 393)6.

 

Jacobsen, S. B. and Wasserburg, G. J. (1980). Sm)Nd isotopic evolution of chondrites. Earth Planet. Sci. Lett. 50, 139)55.

 

Kamber, B. S. and Moorbath, S. Initial Pb of the Amitsoq gneiss revisited: implication for the timing of early Archean crustal evolution in west Greenland. Chem. Geol. 150, 19)41.

 

Kamber, B. S., Moorbath, S. and Whitehouse, M. J.  (1998). Extreme Nd-isotope heterogeneity in the early Archean- fact or fiction? Case histories from northern Canada and West Greenland- Reply. Chem. Geol. 148, 219)24.

 

Keto, L. S. and Jacobsen, S. B. (1987). Nd and Sr isotopic variations of Early Paleozoic oceans. Earth Planet. Sci. Lett. 84, 27)41.

 

Keto, L. S. and Jacobsen, S. B. (1988). Nd isotopic variations of Phanerozoic paleo-oceans. Earth Planet. Sci. Lett. 90, 395)410.

 

Lahaye, Y., Arndt, N., Byerly, G., Chauvel, C., Fourcade, S. and Gruau, G. (1995). The influence of alteration on the trace-element and nd isotopic composition of komatiites. Chem. Geol. 126, 43–64.

 

Lambert, D. D., Morgan, J. W., Walker, R. J., Shirey, S. B., Carlson, R. W., Zientek, M. L. and Koski, M. S. (1989). Rhenium)osmium and samarium)neodymium isotopic systematics of the Stillwater Complex. Science 244, 1169)74.

 

Ling, H. F., Burton, K. W., O’Nions, R. K., Kamber, B. S., von Blanckenburg, F., Gibb, A. J. and Hein, J. R. (1997). Evolution of Nd and Pb isotopes in Central Pacific seawater from ferromanganese crusts. Earth Planet. Sci. Lett. 146, 1)12.

 

Lugmair, G. W. and Marti, K. (1977). Sm)Nd)Pu timepieces in the Angra dos Reis meteorite. Earth Planet. Sci. Lett. 35, 273)84.

 

Lugmair, G. W. and Marti, K. (1978). Lunar initial 143Nd/144Nd : differential evolution of the lunar crust and mantle. Earth Planet. Sci. Lett. 39, 349)57.

 

Lugmair, G. W. and Scheinin, N. B. (1975). Sm)Nd systematics of the Stannern meteorite. Meteoritics 10, 447)8 (abstract).

 

Lugmair, G. W., Scheinin, N. B., and Marti, K. (1975). Search for extinct 146Sm, I. The isotopic abundance of 142Nd in the Juvinas meteorite. Earth Planet. Sci. Lett. 27, 79)84.

 

McCulloch, M. T. and Compston, W. (1981). Sm)Nd age of Kambalda and Kanowna greenstones and heterogeneity in the Archean mantle. Nature 294, 322)7.

 

McCulloch, M. T. and Wasserburg, G. J. (1978). Sm)Nd and Rb)Sr chronology of continental crust formation. Science 200, 1003)11.

 

McLennan, S. M., McCulloch, M. T., Taylor, S. R. and Maynard, J. B. (1989). Effects of sedimentary sorting on neodymium isotopes in deep-sea turbidites. Nature 337, 547)9.

 

Michard, A., Albarede, F., Michard, G., Minster, J. F. and Charlou, J. L. (1983). Rare-earth elements and uranium in high-temperature solutions from East Pacific Rise hydrothermal vent field (13 oN). Nature 303, 795–7.

 

Mildowski, A. E. and Zalasiewicz, J. A. (1991). Redistribution of rare earth elements during diagenesis of turbidite/hemipelagite mudstone sequences of Llandovery age from central Wales. In: Morton, A. C. et al. (Eds), Developments in Sedimentary Provenance Studies. Geol. Soc. Spec. Pap. 56, pp. 789–95.

 

Moorbath, S. (1976). Age and isotope constraints for the evolution of Archaean crust. In: Windley, B. F. (Ed.), The Early History of the Earth, Wiley, 351)60.

 

Moorbath, S., Powell, J. L. and Taylor, P. N. (1975). Isotopic evidence for the age and origin of the grey gneiss complex of the southern Outer Hebrides, Scotland. J. Geol. Soc. Lond. 131, 213)22.

 

Moorbath, S. and Whitehouse, M. J. (1996). SmNd isotope data and Earth’s evolution: Comment. 273, 1878.

 

Moorbath, S., Whitehouse, M. J. and Kamber, B. S. (1997). Extreme Nd-isotope heterogeneity in the early Archean– fact or fiction? Case histories from northern Canada and West Greenland. Chem. Geol. 135, 213)31.

 

Mork, M. B. E. and Mearns, E. W. (1986). Sm)Nd isotopic systematics of a gabbro)eclogite transition. Lithos 19, 255)67.

 

Nagler, Th. F. and Kramers, J. D. (1998). Nd isotopic evolution of the upper mantle during the Precambrian: models, data and the uncertainty of both. Precamb. Res. 91 233)252.

 

Nelson, B. K. and DePaolo, D. J. (1984). 1,700-Myr greenstone volcanic successions in southwestern North America and isotopic evolution of Proterozoic mantle. Nature 312, 143–6.

 

Nelson, B. K. and DePaolo, D. J. (1985). Rapid production of continental crust 1.7 to 1.9 b.y. ago: Nd isotopic evidence from the basement of the North American mid-continent. Geol. Soc. Amer. Bull. 96, 746)54.

 

Nelson, B. K. and DePaolo, D. J. (1988). Application of Sm)Nd and Rb)Sr isotope systematics to studies of provenance and basin analysis. J. Sed. Petrol. 58, 348)57.

 

Notsu, K., Mabuchi, H., Yoshioka, O., Matsuda, J. and Ozima, M. (1973). Evidence of the extinct nuclide 146Sm in ‘Juvinasachondrite. Earth Planet. Sci. Lett. 19, 29)36.

 

Nunes, P. D. (1981). The age of the Stillwater complex: a comparison of U)Pb zircon and Sm)Nd isochron systematics. Geochim. Cosmochim. Acta 45, 1961)3.

 

Nutman, A. P., Bennett, V. C., Friend, C. R. L. and McGregor, V. R. (2000). The early Archean Itsaq Gneiss Complex of southern West Greenland: The importance of field observations in interpreting age and isotopic constraints for early terrestrial evolution. Geochim. Cosmochim. Acta 64, 3035)60.

Ohlander, B., Ingri, J., Land, M. and Schoberg, H. (2000). Change of SmNd isotope composition during weathering of till. Geochim. Cosmochim. Acta 64, 813–20.

 

O’Nions, R. K. (1984). Isotopic abundances relevant to the identification of magma sources. Phil. Trans. Roy. Soc. Lond. A 310, 591)603.

 

O’Nions, R. K., Carter, S. R., Cohen, R. S., Evensen, N. M. and Hamilton, P. J. (1978). Pb, Nd and Sr isotopes in oceanic ferromanganese deposits and ocean floor basalts. Nature 273, 435)8.

 

O’Nions, R. K., Frank, M., von Blanckenburg, F. and Ling, H.-F. (1998). Secular variation of Nd and Pb isotopes in ferromanganese crusts from the Atlantic, Indian and Pacific Oceans. Earth Planet. Sci. Lett. 155, 15)28.

 

O’Nions, R. K., Hamilton, P. J. and Evensen, N. M. (1977). Variations in 143Nd/144Nd and 87Sr/86Sr in oceanic basalts. Earth Planet. Sci. Lett. 34, 13)22.

 

O’Nions, R. K., Hamilton, P. J. and Hooker, P. J. (1983). A Nd isotope investigation of sediments related to crustal development in the British Isles. Earth Planet. Sci. Lett. 63, 229)40.

 

Palmer, M. R. and Elderfield, H. (1986). Rare earth elements and neodymium isotopes in ferromanganese oxide coatings of Cenozoic foraminifera from the Atlantic Ocean. Geochim. Cosmochim. Acta 50, 409–17.

 

Patchett, P. J. and Arndt, N. T. (1986). Nd isotopes and tectonics of 1.9 ) 1.7 Ga crustal genesis. Earth Planet. Sci. Lett. 78, 329)38.

 

Pidgeon, R. T. and Bowes, D. R. (1972). Zircon U/Pb ages of granulites from the central region of the Lewisian, north western Scotland. Geol. Mag. 109, 247)58.

 

Piepgras, D. J. and Wasserburg, G. J. (1980). Neodymium isotopic variations in seawater. Earth Planet. Sci. Lett. 50, 128)38.

 

Piepgras, D. J. and Wasserburg, G. J. (1983). Influence of the Mediterranean Outflow on the isotopic composition of neodymium in waters of the North Atlantic. J. Geophys. Res. 88, 5997)6006.

 

Piepgras, D. J. and Wasserburg, G. J. (1987). Rare earth element transport in the western North Atlantic inferred from Nd isotopic observations. Geochim. Cosmochim. Acta 51, 1257)71.

 

Piepgras, D. J., Wasserburg, G. J. and Dasch, E. J. (1979). The isotopic composition of Nd in different ocean masses. Earth Planet. Sci. Lett. 45, 223)36.

 

Reynolds, B. C., Frank, M. and O’Nions, R. K. (1999). Nd- and Pb-isotope time series from Atlantic ferromanganese crusts: implications for changes in provenance and paleocirculation over the last 8 Myr. Earth Planet. Sci. Lett. 173, 381)96.

Richardson, S. H., Gurney, J. J., Erlank, A. J. and Harris, J. W. (1984). Origin of diamonds in old enriched mantle. Nature 310, 198)202.

 

Rutberg, R. L., Hemming, S. R. and Goldstein, S. L. (2000). Reduced North Atlantic Deep Water flux to the glacial Southern Ocean inferred from neodymium isotope ratios. Nature 405, 935–8.

 

Samson, S. D., McClelland, W. C., Patchett, P. J., Gehrels, G. E. and Anderson, R. G. (1989). Evidence from neodymium isotopes for mantle contributions to Phanerozoic crustal genesis in the Canadian Cordillera. Nature 337, 705)9.

 

Shaw, H. F. and Wasserburg, G. J. (1985). Sm)Nd in marine carbonates and phosphates: implications for Nd isotopes in seawater and crustal ages. Geochim. Cosmochim. Acta 49, 503)18.

 

Smith, A. D. and Ludden, J. N. (1989). Nd isotopic evolution of the Precambrian mantle. Earth Planet. Sci. Lett. 93, 14)22.

 

Staudigel, H., Doyle, P. and Zindler, A. (1985). Sr and Nd isotope systematics in fish teeth. Earth Planet. Sci. Lett. 76, 45)56.

 

Stille, P. and Clauer, N. (1986). Sm)Nd isochron-age and provenance of the argillites of the Gunflint Iron Formation in Ontario, Canada. Geochim. Cosmochim. Acta 50, 1141)6.

 

Stordal, M. C. and Wasserburg, G. J. (1986). Neodymium isotopic study of Baffin Bay water: sources of REE from very old terranes. Earth Planet. Sci. Lett. 77, 259)72.

 

Tachikawa, K., Jeandel, C. and Roy-Barman, M. (1999). A new approach to the Nd residence time in the ocean: the role of atmospheric inputs. Earth Planet. Sci. Lett. 170, 433)46.

 

Taylor, S. R., McLennan, S. M. and McCulloch, M. T. (1983). Geochemistry of loess, continental crustal composition and crustal model ages. Geochim. Cosmochim. Acta 47, 1897)1905.

 

Thurston, P. C., Osmani, I. A. and Stone, D. (1991). Northwest Superior province: review and terrane analysis. In: Thurston, P. C., Williams, H. R., Sutcliffe, R. H. and Stott, G. M. (Eds), Geology of Ontario. Ontario Geol. Surv. Spec. Vol. 4, 81)139.

 

Tugarinov, A. I. and Bibikova, Y. V. (1976). Evolution of the chemical composition of the Earth’s crust. Geokhimiya 1976, (8) 1151)9.

 

Vance, D. and Burton, K. (1999). Neodymium isotopes in planktonic foraminifera: a record of the response of continental weathering and ocean circulation rates to climate change. Earth Planet. Sci. Lett. 173, 365)79.

 

Vance, D. and O’Nions, R. K. (1990). Isotopic chronometry of zoned garnets: growth kinetics and metamorphic histories. Earth Planet. Sci. Lett. 97, 227)40.

VonderHaar, D. L., Mahoney, J. J. and McMurtry, G. M. (1995). An evaluation of strontium isotopic dating of ferromanganese oxides in a marine hydrogeneous ferromanganese crust. Geochim. Cosmochim. Acta 59, 4267)77.

 

Wasserburg, G. J., Jacobsen, S. B., DePaolo, D. J., McCulloch, M. T. and Wen, T. (1981). Precise determination of Sm/Nd ratios, Sm and Nd isotopic abundances in standard solutions. Geochim. Cosmochim. Acta 45, 2311)23.

 

West, G. F. (1980). Formation of continental crust. In: Strangway, D. W. (Ed.), The Continental Crust and its Mineral Deposits. Geol. Assoc. Canada Spec. Pap. 8, 117)48.

 

Whitehouse, M. J. (1988). Granulite facies Nd-isotopic homogenisation in the Lewisian complex of northwest Scotland. Nature 331, 705)7.

 

Whitehouse, M. J., Kamber, B. S. and Moorbath, S. M. (1999). Age significance of U–ThPb zircon data from early Archean rocks of west Greenland– a reassessment based on combined ion-microprobe and imaging studies. Chem. Geol. 160, 201–24.

 

Williams, H. R., Stott, G. M., Thurston, P. C., Sutcliffe, R. H., Bennett, G., Easton, R. M. and Armstrong, D. K. (1992). Tectonic evolution of Ontario: summary and synthesis. In: Thurston, P. C., Williams, H. R., Sutcliffe, R. H. and Stott, G. M. (Eds), Geology of Ontario. Ontario Geol. Surv. Spec. Vol. 4, 1255)1332.

 

Wust, G. (1924). Florida und Antillenstrom. Veroffentl. Inst. Meeresh. Univ. Berlin 12, 1)48.